Approach to multifunctional device platform with epitaxial graphene on transition metal oxide
نویسندگان
چکیده
Heterostructures consisting of two-dimensional materials have shown new physical phenomena, novel electronic and optical properties, and new device concepts not observed in bulk material systems or purely three dimensional heterostructures. These new effects originated mostly from the van der Waals interaction between the different layers. Here we report that a new optical and electronic device platform can be provided by heterostructures of 2D graphene with a metal oxide (TiO2). Our novel direct synthesis of graphene/TiO2 heterostructure is achieved by C60 deposition on transition Ti metal surface using a molecular beam epitaxy approach and O2 intercalation method, which is compatible with wafer scale growth of heterostructures. As-grown heterostructures exhibit inherent photosensitivity in the visible light spectrum with high photo responsivity. The photo sensitivity is 25 times higher than that of reported graphene photo detectors. The improved responsivity is attributed to optical transitions between O 2p orbitals in the valence band of TiO2 and C 2p orbitals in the conduction band of graphene enabled by Coulomb interactions at the interface. In addition, this heterostructure provides a platform for realization of bottom gated graphene field effect devices with graphene and TiO2 playing the roles of channel and gate dielectric layers, respectively.
منابع مشابه
Afrl-rx-wp-ja-2016-0201 Approach to Multifunctional Device Platform with Epitaxial Graphene on Transition Metal Oxide (postprint)
متن کامل
Large area molybdenum disulphide- epitaxial graphene vertical Van der Waals heterostructures
Two-dimensional layered transition metal dichalcogenides (TMDCs) show great potential for optoelectronic devices due to their electronic and optical properties. A metal-semiconductor interface, as epitaxial graphene - molybdenum disulfide (MoS2), is of great interest from the standpoint of fundamental science, as it constitutes an outstanding platform to investigate the interlayer interaction i...
متن کاملUltraviolet detectors based on annealed zinc oxide thin films: epitaxial growth and physical characterizations
In this report, ultraviolet (UV) detectors were fabricated based on zinc oxide thin films. The epitaxial growth of zinc oxide thin films was carried out on bare glass substrate with preferred orientation to (002) plane of wurtzite structure through radio frequency sputtering technique. The structural properties indicated a dominant peak at 2θ=34.28º which was matched with JCPDS reference card N...
متن کاملElectrocatalytic Determination of Glutathione Using Transition Metal Hexacyanoferrates (MHCFs) of Copper and Cobalt Electrode Posited on Graphene Oxide Nanosheets
A glassy carbon electrode was modified with graphene oxide nanosheets and a hybrid of copper-cobalt hexacyanoferrate. The nanocomposite was characterized by cyclic voltammetry, FT-IR and scanning electron microscopy. Cyclic voltammetry showed a stable and reversible redox pair with surface confined characteristics in phosphate buffer solution (0.1 M, pH 3). Hydrodynamic amperometry was used for...
متن کاملChemical gating of epitaxial graphene through ultrathin oxide layers.
We achieved a controllable chemical gating of epitaxial graphene grown on metal substrates by exploiting the electrostatic polarization of ultrathin SiO2 layers synthesized below it. Intercalated oxygen diffusing through the SiO2 layer modifies the metal-oxide work function and hole dopes graphene. The graphene/oxide/metal heterostructure behaves as a gated plane capacitor with the in situ grow...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 5 شماره
صفحات -
تاریخ انتشار 2015